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Ask experts Expert Question: electrolysis of NaCl with C2H5OH
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Manasi (3976)

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20% aqueous NaCl solution containing ethyl alcohol when subjected to electrolysis produce
 
a) C2H5OH
b) CH3CHO
c) CHCl3
d) CCl3CHO

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CyBorG (1574)

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Mostly the answer is d)CCl3CHO as the chlorine obtained by the electrolysis will oxidise ethyl alcohol to acetaldehyde and then it undergoes halogenation and finally chloral will be obtained.

-ADARSH
NITK Surathkal

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Manasi (3976)

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even i think so, bt not very sure, lets see what experts have to say regarding this...

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smriti.mathur (454)

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(d) CCl3CHO
On electrolysis, Chlorine will be obtained, which is an oxidizing agent. Alcohol will be oxidized to acetaldehyde which will be further halogenated to chloral.

Lecturar, Organic Chemistry
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Manasi (3976)

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thank u ma'm

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arun-rashi (1128)

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no here final product is CHCl3 because by the electrolysis formation of NaOH chlorine takes place which gives haloform test with etanol.
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